密闭取样煤样瓦斯解吸规律实验研究

Experimental study on gas desorption characteristics of coal samples collected by sealed sampling

  • 摘要: 为研究密闭取样煤样瓦斯解吸规律,根据密闭取样工艺流程,将密闭取样煤样瓦斯解吸进程划分为逸散阶段、密闭解吸阶段和常压自然解吸阶段,开展了密闭取样煤样瓦斯解吸实验,分析了密闭取样煤样瓦斯累计解吸量与解吸速率的变化特征。结果表明:① 在密闭解吸阶段,随着吸附平衡压力增大,煤样瓦斯累计解吸量和初始瓦斯解吸速率均呈增大趋势;但随着“等容变压”解吸的持续,瓦斯解吸能力受限,瓦斯解吸速率逐渐减小,瓦斯累计解吸量逐渐趋于稳定。② 在常压自然解吸阶段,随着吸附平衡压力增大,瓦斯累计解吸量和初始瓦斯解吸速率逐渐增大,且受密闭解吸阶段游离态瓦斯解吸影响,该阶段初始时刻的瓦斯解吸速率高于密闭解吸阶段;随着解吸时间增加,瓦斯累计解吸量逐渐趋于稳定。③ 孙重旭式能较好描述常压自然解吸过程瓦斯解吸规律,解吸指标随着吸附平衡压力增大而增大,而解吸指数在不同吸附平衡压力下基本保持稳定,表明密闭取样煤样在较高吸附平衡压力条件下具有更强的解吸能力,瓦斯解吸速率变化情况在不同吸附平衡压力下基本一致。

     

    Abstract: In order to study the gas desorption characteristics of coal samples collected by sealed sampling, according to the sealed sampling procedure, the gas desorption process was divided into the diffusion stage, the sealed desorption stage, and the atmospheric natural desorption stage. Gas desorption experiments of coal samples collected by sealed sampling were conducted, and the variation characteristics of cumulative gas desorption and desorption rate were analyzed. The results showed that: ① In the sealed desorption stage, with the increase of adsorption equilibrium pressure, both the cumulative gas desorption and the initial gas desorption rate increased. However, with the continuous isochoric variable-pressure desorption, the gas desorption capacity was limited, the gas desorption rate gradually decreased, and the cumulative gas desorption gradually tended to be stable. ② In the atmospheric natural desorption stage, with the increase of adsorption equilibrium pressure, both the cumulative gas desorption and the initial gas desorption rate gradually increased. Due to the influence of free gas desorption in the sealed desorption stage, the initial gas desorption rate at this stage was higher than that in the sealed desorption stage. With the increase of desorption time, the cumulative gas desorption gradually tended to be stable. ③ The Sun Chongxu equation well described the gas desorption characteristics in the atmospheric natural desorption process. The desorption indicator increased with the increase of adsorption equilibrium pressure, while the desorption exponent basically remained stable under different adsorption equilibrium pressures, indicating that coal samples collected by sealed sampling had stronger desorption capacity under higher adsorption equilibrium pressure, and the variation of gas desorption rate was basically consistent under different adsorption equilibrium pressures.

     

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