Abstract: For lack of quantitative analysis method for current coal mine emergency rescue organization structure, order degree of organization structure was defined from timeliness and quality of information transmission, and flexibility degree of organization structure was calculated by use of variation entropy based on analysis of characteristics of coal mine emergency rescue organization and entropy theory, then models of order degree and flexibility degree of coal mine emergency rescue organization structure were established. The application results show that accurate analysis of coal mine emergency rescue organization structure can be realized through order degree and flexibility degree.